Effect of operating conditions on the yield of 2-hydroxyterephthalic acid for tracing OH radical in an electrochemical process

Citation:
Hoang NT, Mwazighe FM. "Effect of operating conditions on the yield of 2-hydroxyterephthalic acid for tracing OH radical in an electrochemical process." Moscow University Chemistry Bulletin. 2022;77(5):286-299.

Abstract:

The boron-doped diamond electrode has been widely applied in electrochemical process for wastewater treatment based on the generation of hydroxyl radicals (•OH). This study investigated the formation efficiency of 2-HTA through the interaction between •OH radical and terephthalic acid (TA) to monitor the •OH formation. Results show that the 2-HTA formation efficiency did not depend on the initial concentration of scavenger (here, TA) in the investigated range of 0.1 to 1 mM TA. Meanwhile, other factors, such as current density, supporting electrolyte, sodium hydroxide have a significant influence. The optimal condition was established: concentration of electrolyte (0.05 M Na2SO4); initial concentration of TA (0.1 mM); concentration of NaOH (1 mM); current density (j = 20 mA cm–2). The selectivity of TA was evaluated by Faradaic efficiency (η) and hydroxylation yield (γTAOH), indicating that Faradaic efficiency (η) for 2-HTA formation was in the range of 10–5–10–7, while the hydroxylation yield of •OH (γTAOH) into 2-HTA was 0.03–0.12.

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